UNITED STATES
SECURITIES AND EXCHANGE COMMISSION
Washington, D.C. 20549
FORM 6-K
REPORT OF FOREIGN PRIVATE ISSUER
PURSUANT TO RULE 13a-16 OR 15d-16 UNDER
THE SECURITIES EXCHANGE ACT OF 1934
For the month of October, 2026
Commission File Number 001-34175
| ECOPETROL S.A. |
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(Exact name of registrant as specified in its charter)
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| N.A. |
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(Translation of registrant’s name into English)
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| COLOMBIA |
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(Jurisdiction of incorporation or organization)
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| Carrera 13 No. 36 – 24 |
| BOGOTA D.C. – COLOMBIA |
| (Address of principal executive offices) |
Indicate by check mark whether the registrant files or will file annual reports under cover of Form 20-F or Form 40-F.
Form 20-F x Form 40-F ¨
Indicate by check mark if the registrant is submitting the Form 6-K in paper as permitted by Regulation S-T Rule 101(b)(1)
Yes ¨ No x
Indicate by check mark if the registrant is submitting the Form 6-K in paper as permitted by Regulation S-T Rule 101(b)(7)
Yes ¨ No x
Indicate by check mark whether the registrant by furnishing the information contained in this form is also thereby furnishing the information to the Commission pursuant to Rule 12g3-2(b) under the Securities Exchange Act of 1934.
Yes ¨ No x
If “Yes” is marked, indicate below the file number assigned to the registrant in connection with Rule 12g3-2(b): 82- N/A
SIGNATURES
Pursuant to the requirements of the Securities Exchange Act of 1934, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized.
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Ecopetrol S.A. |
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By: |
/s/ Alfonso Camilo Barco |
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Name: |
Alfonso Camilo Barco |
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Title: |
Chief
Financial Officer |
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Date: October 21,
2026

Ecopetrol's "New Era" Advances with the
Appointment of the Executive Vice President of Energies for the Transition and Two Legal Representatives
Bogota, D.C.,
October 21st, 2026
Ecopetrol S.A. (BVC: ECOPETROL; NYSE: EC) (the
"Company") announces that its Board of Directors has appointed Armando José Cuello Navarro as Executive Vice President
of Energy Transition. He is expected to join the Company's executive leadership team no later than October 27, 2026, as part of the strategy
to strengthen Ecopetrol's senior management structure in its “New Era.”
Mr. Cuello Navarro holds a degree in Industrial
Engineering from Universidad de los Andes and a Master of Business Administration (MBA) from IE Business School. He brings more than 17
years of executive experience in the energy sector across Colombia and Peru, having held leadership positions at Compañía
Energética de Occidente, Promigas Perú, and Promigas S.A. E.S.P., where he oversaw strategy, investments, financial performance,
and corporate governance.
His professional background combines public sector
experience, having served as Colombia's Deputy Minister of Energy, with executive management responsibilities in business expansion and
infrastructure project development.
In addition, Armando José has served on
the boards of directors of several energy sector companies and has led organizational transformation and digitalization initiatives aimed
at enhancing operational efficiency.
At Ecopetrol, some of his key challenges will
include advancing Colombia's energy security and sovereignty through a diversified energy matrix, strengthening alignment with the national
energy policy, supporting the country's natural gas supply reliability, and developing profitable projects to optimize the energy portfolio
while generating value and promoting long-term sustainability for the Ecopetrol Group.
Furthermore, the Board of Directors approved today
the appointment of Camilo Andrés Rojas Castro as Principal Legal Representative for Goods and Services Procurement matters of Ecopetrol
S.A., as well as the appointment of Mauricio Gutiérrez Dangond as First Alternate to the Company's General Legal Representative.
These appointments will become effective upon completion of the corresponding legal formalities.
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Ecopetrol is the largest company in Colombia and
one of the main integrated energy companies in the American continent, with more than 19,000 employees. In Colombia, it is responsible
for more than 60% of the hydrocarbon production of most transportation, logistics, and hydrocarbon refining systems, and it holds leading
positions in the petrochemicals and gas distribution segments. With the acquisition of 51.4% of ISA’s shares, the company participates
in energy transmission, the management of real-time systems (XM), and the Barranquilla–Cartagena coastal highway concession. At
the international level, Ecopetrol has a stake in strategic basins in the American continent, with drilling and exploration operations
in the United States (Permian basin and the Gulf of Mexico), Brazil, and Mexico, and, through ISA and its subsidiaries, Ecopetrol holds
leading positions in the power transmission business in Brazil, Chile, Peru, and Bolivia, road concessions in Chile, and the telecommunications
sector.
This release contains statements that may be considered
forward-looking statements within the meaning of Section 27A of the U.S. Securities Act of 1933, as amended, and Section 21E of the U.S.
Securities Exchange Act of 1934, as amended. All forward-looking statements, whether made in this release or in future filings or press
releases, or orally, address matters that involve risks and uncertainties, including in respect of the Company’s prospects for
growth and its ongoing access to capital to fund the Company’s business plan, among others. Consequently, changes in the following
factors, among others, could cause actual results to differ materially from those included in the forward-looking statements: market
prices of oil & gas, our exploration, and production activities, market conditions, applicable regulations, the exchange rate, the
Company’s competitiveness and the performance of Colombia’s economy and industry, to mention a few. We do not intend and
do not assume any obligation to update these forward-looking statements.
For more information, please contact:
Investor Relations Office
Email: investors@ecopetrol.com.co
Corporate Communications (Colombia)
Email: _noticias@ecopetrol.com.co